Summer Research Experience for Undergraduates
Undergraduate Institution: Mercer University
Major: Electrical Engineering
REU Advisor: Jos Heremans
Project Title: Investigating thermoelectric properties of BiSb
The purpose if this investigation is to establish the processes necessary to synthesize and characterize BiSb alloys to be used as a thermoelectric material. BiSb has been investigated in the past for this purpose, but recent theoretical studies have indicated that a significantly higher Thermoelectric figure of merit (zT) can be found in BiSb alloys with new fabrication techniques. BiSb samples are synthesized from Bi2O3 and Sb2O3 powders. The sample is then thermoelectrically measured in a cryostat across the temperature range of 77K-400K. The data is then extensively analyzed in a LabView routine written by Professor Heremans.
Name: Taylor Herrera
Undergraduate Institution: New Mexico Highlands University
Major: Computer Science
REU Advisors: Chris Hammel and Denis Pelekhov
Project Title: Magnetic field calculations of a micro-magnetic particle for the localized ferromagnetic resonance
We calculate magnetic fields emanating from a point dipole and create their maps in a 3-dimensional space. When a DC current flows through a bilayer system of ferromagnetic (FM) and normal metal (NM), the spin-orbit interaction on its interface causes the spin torque exerted on the FM. Above the certain threshold current, it can induce an auto-oscillation of a coherent magnetization precession, the same phenomenon observed in ferromagnetic resonance by applying a microwave field. We are interested in observing the auto-oscillation of FMR modes localized by a dipolar field generated from a micron-sized magnetic particle in the bilayer films consisting of the permalloy(Py, FM) and platinum(Pt, NM). In this project, the calculation of the magnetic field from a magnetic particle is essential for analyzing the data. Here we make a program that calculates a point dipole field and constructs its 3D map using a Python, assuming that our magnetic particle in a spherical shape has the same field from a point dipole with the same magnetic moment. The program is capable of imaging the magnitude and direction of the field in our assigned 3D space and the dipole in our calculation can be located at any position that we want.
Name: Jimmy Kuznar
Undergraduate Institution: Columbus State Community College
Major: Chemical Engineering
REU Advisor: David McComb
Project Title: Digital image analysis of micro/nanostructures within dentin
There are three main layers to teeth. Enamel is the outermost layer followed by dentin and pulp. Dentin is produced by odontoblasts  which are cells located in the pulp of the tooth. Dentin is a composite material that mainly contains inorganic hydroxyapatite crystals (Ca5(PO4)3(OH)) and organic collagen matrix proteins . Dentin contains microtubular structures that are present throughout at varying quantities and diameters . Some of these microtubules have channel like structures that branch out from the tubules through the peritubular dentin and in some cases to other microtubules. These channel-like structures are referred to as ‘nanotubules’. This research seeks to better visualize the dentin tubules and peritubular dentin. How these micro and nano tubule features are positioned relative to each other can potentially provide significant insight into the diffusion of ionic species throughout the intertubular dentin in three-dimensional (3D) space.
Name: Sindy Lauricella
Undergraduate Institution: New Mexico Highlands University
Major: Environmental Geology
REU Advisor: Ezekiel Johnston-Halperin
Project Title: Magnetic characterization of solvent resistance in vanadium tetracyanoethylene (V[TCNE]2)
Organic-based magnetic materials have beneficial applications such as electronic materials, room temperature magnetic ordering, and mechanical flexibility. The organic-based magnet we will be focusing on throughout this research is Vanadium tetracyanoethylene V[TCNE]x~2, a semiconducting ferrimagnet that displays room temperature magnetic ordering. It is considered a metal organic hybrid system because it’s combining an organic ligand with a metal atom. There are few projects that focus on different ways to analyze the limits of manipulating V[TCNE] one is replacing TCNE ligand with new ligands that are designed then adding dichloromethane to test weather the new ligands can make air-stable ferrimagnets. Another approach is adding solvents to metals and identify if there are any magnetic changes in the structure of V[TCNE]. This research will consist of synthesizing thin films of V[TCNE] with V(CO)6 and TCNE via Chemical Vapor Deposition (CVD) in a glass furnace. The grown CVD films decompose in air that result in loss of magnetic properties, which is why the process is done in an argon glove box. Once completed our V[TCNE] we will use the Superconducting Quantum Interference Device (SQUID) that helps identify the global magnetic ordering of the sample by measuring magnetization. SQUID will be used before adding a dichloromethane solvent to record the control measure of V[TCNE] and after the solvent is added. We are adding dichloromethane solvent to determine weather or not our V[TCNE] films are resistant to the solvent and see if there are changes in the magnetic field and in the microscopic scale. Electronic paramagnetic Resonance (EPR) will be used to identify what’s inside the material and see how much change has occurred in the signatures. Signatures are peaks shown in the data that we will later review to identify if the material continues to have V[TCNE] after adding the dichloromethane solvent.
Name: Andrew Lininger
Undergraduate Institution: University of Akron
REU Advisor: Jay Gupta
Project Title: Thin-film Cu2O growth and surface structure on Cu(100): An STM study
The growth and surface structure of thin-film Cu2O on a crystalline Cu (100) surface has been studied through low temperature ultra-high vacuum scanning tunneling microscopy (UHV-STM). Two distinct regions are observed on the surface: adlayer terraces, exhibiting characteristic step edges of 4Å, and flat patches with a distinctive striped pattern. The adlayer is identified as oxidation of the Cu (100) surface through atomic resolution of the ‘ladder’ structure (missing-row reconstruction), with rectangular depressions on 3.7Å. The surface is observed under cold in situ dosing of CO2. The flat striped patches are associated with the Cu2O (111) surface, identified by two distinct patterns of protrusions: a (1×1) periodicity hexagonal lattice with spacing 3.1Å and an atomically resolved (√3x√3)R30° periodicity lattice with spacing of 5.2Å. The first structure is attributed to individual copper ions on the stoichiometric ideal (111) surface and the second to oxygen vacancies and the nearest-neighbor Cu atoms on the same surface. This demonstrates that similar structures occur on monolayer Cu2O (111) as on the bulk Cu2O (111) surface.
Name: Omar Mansour
Undergraduate Institution: NThe Ohio State University
Major: Physics and Electrical Engineering
REU Advisor: Nandini Trivedi
Project Title: Quantum spin liquids
Name: Sanjana Pappu
Undergraduate Institution: University of Texas, Austin
Major: Chemical Engineering
REU Advisor: Wolfgang Windl
Project Title: Electronic structure of in-plane functionalized graphane analog interface
As research on 2D materials and functionalization of 2D crystals continues, we focus on the effects full functionalization of -H and -CH3 ligands have on a buckled germanene backbone. The crystal structures of hydrogen-terminated germanene and methyl-terminated germanene are simulated using crystal modeling software to observe the properties of both materials and determine whether forming a junction in an interface is practical. The work function and density of states of each 2D structure are analyzed to confirm if the ligands can work well in an interface. By simulating the crystal structure of 2D graphane analog interface and performing electronic calculations using Density Functional Theory methods, we can understand more about ligand chemistry on interfaces. Computational modeling of the structures provides novel insights into the properties and electronic structures of the materials. Successful theoretical results yield for potential synthesis of the materials to be used in the future for devices.
Name: Erin Snyder
Undergraduate Institution: Rollins College
REU Advisor: Joshua Goldberger
Project Title: Materials with anisotropic Seebeck behavior for transverse thermoelectrics
Alternative energy sources are becoming more desirable to replace other sources that have significant environmental effects or lose a large fraction of the generated energy as waste heat. One solution to this problem is a thermoelectric device, which creates a current from a change in voltage produced by a heat gradient. Typical thermoelectric devices require two separate materials containing different majority carrier types, both p-type and n-type. This allows holes and electrons to travel from the hot end to the cold end, respectively, thereby creating a difference in electrical potential. If one material were able to possess both p-type and n-type behavior in perpendicular axes, as seen through an anisotropic Seebeck coefficient, these devices would offer more practical device engineering as well as geometric adaptability. Several possible candidates were identified by their band structure indicating both p-type and n-type character, including CaAgBi, CaAgSb, CaCuBi, and CaCuSb, and formed using inorganic chemistry crystal synthesis. Phase-pure samples were synthesized by reacting stoichiometric amounts at high temperatures followed by slow cooling and were characterized by X-Ray Diffraction and Raman Spectroscopy. The next step towards transverse thermoelectric devices is creating large, single crystals to find axis dependence in Seebeck coefficients.
2016 Summer REU Student Information & Research Abstracts
Name: Ryan Bailey-Crandell
Undergraduate Institution: Oregon State University
REU Advisor: Roland Kawakami
Project Title: Characterizing charge and spin transport in graphene: From instrumentation to measurement
Spintronics aims to se the spin degree of freedom of electrons for logic operation and information storage. Recently, it has been proposed that high speed, low power consumption logic operations, as well as reconfigurable logic devices can be achieved with spintronics. To achieve the goals, it is required to develop a device that can reliably generate, transport, and detect spin. Graphene, a single atomic layer of graphite carbon atoms, is one of the most promising materials for spintronic devices. Graphene has shown promising qualifications for spin transport due to its gate-tunable electronic properties, long spin lifetime and spin diffusion length at room temperature. However, the lack of spin orbit coupling makes it hard to generate and detect spin within graphene, which is a hindrance for certain avenues of application. To achieve spin logic with graphene, it is necessary to develop a method to overcome this issue. We focus on generating spin orbit coupling in graphene, as this would allow control of spin signals in a graphene transport.
Name: Forrest Elliot